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Ea (Wxdt-N, :NT)n^esQ. vQN)n  !"#$%&'()*+,-./0123456789:;<=>?@ABCDEFGHIJKLMNOPQRSTUVWXYZ[\]^_`abcdefghijklmnopqrstuvwxyz|}~Root EntrydO) Pictures+Current User5SummaryInformation({5PowerPoint Document(DocumentSummaryInformation8l 0|( 0D[SOes New Roman 7|dv 0|( 0 DArialNew Roman 7|dv 0|( 0"0DWingdingsRoman 7|dv 0|( 0 ` .  @n?" dd@  @@`` X *r&      !"#$%&'( ) /b$crtdtPȏxa+b$%&BUZ鈣ga+b$Yڑ]}D>+b$ +o@볚lݰ\+b$PR|B9 +b$F+_9-Vq(x +b$]wNPU`]Z+b$4&?c>Ca +b$_Di1cA\+b$gө0r'o9Oc+b$2%{sQ#X1+b$ FT+b${L0ox6]+b$hgQ1J帋E}k K!+b$7-1. S^si_ D   Sf[S^ g_ gba, (gPgv'lS, pqRS^g_; (Wnonzzl-Nv'lSR_ba. vnx g_baKNR. FOh_ُy_ba, R gsvi_.Sf[S^vs, /fNUSMOeQSm^v9eSϑ:NW@xegxvzv. bNNS^ 2N2O5 4NO2 + O2 :NORNxvz. * $lN s^GWs >   XKm_ NO2Sm^SSh:yS^s, R(W t1  t2 ُkȇvs^GWs:N: +  6 ,(W t2  t3 ُkȇvs^GWs:N: x $  N wes >(Wxvzq_TS^svV }e, ~8^(u0RgNe;RvS^s. ُe, (us^GWs1\>f_||, V:Nُkȇ, s(WSS, q_TV }_N(WSS. J  I         Tt0 e;Rf~R~ves/f t0 evwes vto . 00Nwesv[IN, SNR_~QwesvBll: (1) ZPSm^ ef~V; (2) (Wc[evf~MOn NZPR~; (3) BlQR~ves((uZPVl, ϑQ~k, BlQkT1. gHexd 00 weg, v^^kN!kxdSugvS^, S g^8^\^8^\vxd/f gHev.HQ, RP[ePcяe, KQ geR, ُ1\BlRP[wQ gYvЏR^, sSϑ. wQYYvϑ/f gHexdv_agN. N~xdvS^irvRP[v;`ϑ_{wQYN*NgNOvϑf6q, (a)yxc g)RNS^vۏL, (b)yNSYvQ[xde_/feHev. STTv!kpe`S;`xd!kpevRpe(u p h:y. RIZZDZZ     Z+$  2. ;mST;mSRP[~ 00\wQYYϑ(xdTNS^)vS^irRP[~, y:N;mSRP[~.\wQYYϑ(xdTNS^)vS^irRP[~, y:N;mSRP[~. 00NlQ_:0 SN wQ, RP[~vϑBlؚ, ;mSRP[~vpeϑ\. ُyϑBlyKN:N;mS, (u Ea h:y. Ea (Wxdt-N, :NT)n^esQ. vQN)n^v~sQ|, \(WirtSf[-Nc0 00Ea 'Y, ;mSRP[~peR\, gHexdRpe\, EeS^sba. Z         H)#  N T{|WvS^, ;mS]+R_'Y. YS^: RP[ Nexd, ϑ Nely, Vdk, RP[vϑ NeSS, Ee;mSRP[~_N N/fV[ NSv. FOS)n^N[, ;mSRP[~v~vRpe/fV[ H   fN Ǐ!nr`t 0 X x Ǐ!n`t, \S^-NmS0Rvir(v_‰~gTS^s~Tweg, ُ/fkxdtHQۏvNb. 6q , (Wt-N, YS^v;mS~Tirv~g\elN[ NRNnx[, R N{elǏN YBg, OُNtv^(uS0RP6R .^(uǏ!n`tSf[S^e, S\S^Ǐ z-NSO|RSS`Qh:y(WS^ۏ z  RV N. 00N NO2 + CO = NO + CO2:NO: v   ####+#+#$    A S^irvs^GWϑ; B ;mS~Tirvϑ; C Nirvs^GWϑS^ۏ zSib:N: a) S^irSO|ϑGSؚ, 8T6e Ea; b) S^irRP[cя, b_b;mS~Tir; c) ;mS~TirRbNir, ʑ>eϑ Ea . Ea S w\OckS^v;mS, /fN]f, TGSؚ,S^irs^GWϑGSؚ, ]

e0R~'l-NO Yq.fSm^'YvSO|, ;mSRP[~vpevkSm^\vSO|Y, gHexd!kpeXR, S^R_, ~g, YOpvkpg Yq. (WWCQS^-N, b(W^WCQS^vWCQek-N, S^sTS^irSm^KN, g%Nf6q [A], [B] ^[^v T, vi v N T, /f1u ki N T_wv0 ZZ            '   3. ki vUSMO 00k ZP:NkO|pe, NNOI{_$NOpef6qv. ߘirYc[fS(, >e(WQ{-N; SR\)n^GS0R 400 K, ߘirfNnqq. 00wpQyf[[, yr +Y (Van t Hoff) cQ, )n^kGSؚ 10 K, S^^N,XR0RSegv 2 4 P0ُy\O Van t Hoff ĉR0 00T GSؚ, RP[vs^GWϑGSؚ, gHexdXR, EesR_. Van t Hoff, 1901t^\VY_, ;N]\O:NRRf[xvz, nS[_I{0(WُN-N, ;NN~ Arrhenius lQ_. 1903t^\Sf[VY_;N.]\O:N5uyt. 5Z        S  ) BN.Arrhenius (?N<\LNe) lQ_ k N T vsQ| " R  )n^[S^svq_T, ;NSOs(W[s8^pe k vq_T N. Arrhenius ;`~Nk N T v~lQ_: (1) cpe_ S6q[pe, _: (2) [pe_ 8^(u[pe: _   \ , 4 _-Nk s8^pe Ea ;mS R lSO8^pe T ~[)n^ 0e 6q[pe^, e = 2.71828& & , lge = 0.4343 = 1/2.303 0A cMRVP[, USMO T k 00^(u?N<\LNelQ_, SN:N Ea, A N)n^SS. 1uN T (Wcpe N, Ee[ k vq_T'Y.     *N ;mS(active energy) >r1ulQ_: 00ZP lgk  (1/T) V _Nv~, vQes:N: 00*bݍ:N: lgA. Ee, \OVlSBl Ea T A fW09hnc\OVl, [SBlQ Ea T A. ^Z      !"7-5PSBR[S^sv q_T D  " N PSBR catalyst >  (WS^-N, S^irvpeϑT~b NS, 9eSS^svir(, SPSBR, PSBR9eSS^sv\O(u, y:NPS\O(u; gPSBRSRvS^, y:NPSS^. 9hncvQ[S^svq_T~g, \PSBRۏLR{|: 0000ckPSBR: R_S^^ 0000PSBR: QbaS^^ xOZ=Z     #   RPSBR: ꁫePS\O(u, S.^RPScؚPS'`. 00 Tb NH3 -Nv Fe |PSBR, R Al2O3 SOhbyX'Y; ReQ K2O SOPSBRhb5uP[N[^X'Y. NGWScؚ Fe |vPS;m'`, GW:NS^vRPSBR0 NRNf, N,GWcckPSBR0 "l   l% &$!N PSS^vyrp >  z 1. b'` 00yr[vS^ gyr[vPSBR. 02SO2 + O2 = 2SO3 00a) V2O5, b) NO2, c)Pt 0CO + 2H2 = CH3OH CuO-ZnO-Cr2O3 oSS^ a) Smkxx b) Smkxx + Smxx c) kxxv d) ;m'`ݔ T7hvS^, PSBR N Te, NirS N T. 00CO + 2H2 = CH3OH 00CuO-ZnO- Cr2O3 00CO + 3H2 = CH4 + H2O 00Ni + Al2O3 002KClO3 = 2KCl + O2 000MnO2 004KClO3 = 3KClO4 + KCl 0ePSBR >Z                       9  \%"  2. 9eSS^s, N9eSpRf[penc 00PSBR9eSS^s, Q\;mS, cؚNs, NmSpRf[. Y: 00A + B = AB Ea _'Y. ePSBR, ba 00ReQPSBR K, :gt9eSN: 00A + B + K 0=0AK + B =0AB + K _! V-NSN wQ, NNckS^v;mSQ\N, NS^v;mS_NMNON. Vdk, S^_NR_N. N9eSpRf[penc! SOs^aecMR. 0 0 jZ    H? S&#  &  f(  r  S PXP  X r  S DM  M :  3 A oH  0޽h ? ̙33ro ? KB(uv( / 00DTimes New Roman 7|dv 0|( 0D[SOes New Roman 7|dv 0|( 0 DArialNew Roman 7|dv 0|( 0"0DWingdingsRoman 7|dv 0|( 0 `  ՜.+,0<     ĻʾtĻS$ )Times New RomanArial WingdingsSoaring ѧѧ 7-1. Ӧʸ PowerPoint ʾĸһ ƽ PowerPoint ʾĸPowerPoint ʾĸ ˲ʱ PowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸ7-2. Ӧ һ.ײ PowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸ ״̬ PowerPoint ʾĸPowerPoint ʾĸ7-3. ŨȶԷӦʵӰ һ ö PowerPoint ʾĸPowerPoint ʾĸPowerPoint ʾĸ.ʳ k PowerPoint ʾĸ7-4. ¶ȶԷӦʵӰ PowerPoint ʾĸ.һ.Arrhenius (˹) ʽ k T Ĺϵ PowerPoint ʾĸ (active energy) 7-5߻ԷӦʵ Ӱ һ ߻ catalystPowerPoint ʾĸ ߻Ӧص PowerPoint ʾĸPowerPoint ʾĸ  õʾĸģ õƬ$_Xfounderfounder^v~sQ|, \(WirtSf[-Nc0 00Ea 'Y, ;mSRP[~peR\, gHexdRpe\, EeS^sba. Z         H)#  N T{|WvS^, ;mS]+R_'Y. YS^: RP[ Nexd, ϑ Nely, Vdk, RP[vϑ NeSS, Ee;mSRP[~_N N/fV[ NSv. FOS)n^N[, ;mSRP[~v~vRpe/fV[ H   fN Ǐ!nr`t 0 X x Ǐ!n`t, \S^-NmS0Rvir(v_‰~gTS^s~Tweg, ُ/fkxdtHQۏvNb. 6q , (Wt-N, YS^v;mS~Tirv~g\elN[ NRNnx[, R N{elǏN YBg, OُNtv^(uS0RP6R .^(uǏ!n`tSf[S^e, S\S^Ǐ z-NSO|RSS`Qh:y(WS^ۏ z  RV N. 00N NO2 + CO = NO + CO2:NO: v   ####+#+#$    A S^irvs^GWϑ; B ;mS~Tirvϑ; C Nirvs^GWϑS^ۏ zSib:N: a) S^irSO|ϑGSؚ, 8T6e Ea; b) S^irRP[cя, b_b;mS~Tir; c) ;mS~TirRbNir, ʑ>eϑ Ea . Ea S w\OckS^v;mS, /fN]f, TGSؚ,S^irs^GWϑGSؚ, ]

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